Intramolecular d10–d10 interactions in heterometallic clusters of the transition metals
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Heterometallic triiron-oxo/hydroxo clusters: effect of redox-inactive metals.
A series of tetranuclear oxo/hydroxo clusters comprised of three Fe centers and a redox-inactive metal (M) of various charge is reported. Crystallographic studies show an unprecedented Fe3M(μ4-O)(μ2-OH) core that remains intact upon changing M or the oxidation state of iron. Electrochemical studies reveal that the reduction potentials (E1/2) span a window of 500 mV and depend upon the Lewis aci...
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ژورنال
عنوان ژورنال: Chemical Society Reviews
سال: 2011
ISSN: 0306-0012,1460-4744
DOI: 10.1039/c0cs00102c